The assessment of electrochemical potential differences between a reference electrode and a metallic structure immersed in an electrolyte, typically soil or water, is a common technique in corrosion engineering. This measurement allows for the determination of the thermodynamic driving force for corrosion at the metal-electrolyte interface. As an example, readings obtained on a buried pipeline, when compared to established criteria, can indicate areas prone to corrosion activity, informing maintenance and mitigation strategies.
This form of testing is vital in evaluating the effectiveness of corrosion control systems, such as cathodic protection. Its use has a long history, evolving alongside the development of electrochemical theory and materials science. Benefits include non-destructive assessment, relatively low cost compared to other techniques, and the ability to provide a broad overview of corrosion risk over large areas. These advantages contribute significantly to proactive infrastructure management and the prevention of costly failures.